prikaz prve stranice dokumenta Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries
  Download
PDF 2.44 MB
Scientific paper - Original scientific paper
Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries
Nano-Micro Letters, 13 (2021), 1; 60. https://doi.org/10.1007/s40820-020-00581-4
Chen, Kai; Kim, Seonghee; Je, Minyeong; Choi, Heechae; Shi, Zhicong; Vladimir, Nikola; Kim, Kwang Ho; Li, Oi Lun

Cite this document

Chen, K., Kim, S., Je, M., Choi, H., Shi, Z., Vladimir, N. ... Li, O. L. (2021). Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries. Nano-Micro Letters, 13. (1). doi: 10.1007/s40820-020-00581-4

Chen, Kai, et al. "Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries." Nano-Micro Letters, vol. 13, no. 1, 2021. https://doi.org/10.1007/s40820-020-00581-4

Chen, Kai, Seonghee Kim, Minyeong Je, Heechae Choi, Zhicong Shi, Nikola Vladimir, Kwang Ho Kim and Oi Lun Li. "Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries." Nano-Micro Letters 13, no. 1 (2021). https://doi.org/10.1007/s40820-020-00581-4

Chen, K., et al. (2021) 'Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries', Nano-Micro Letters, 13(1). doi: 10.1007/s40820-020-00581-4

Chen K, Kim S, Je M, Choi H, Shi Z, Vladimir N, and sur.. Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries. Nano-Micro Letters [Internet]. 2021 January 21 [cited 2024 December 21];13(1). doi: 10.1007/s40820-020-00581-4

K. Chen, et al., "Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries", Nano-Micro Letters, vol. 13, no. 1, January 2021. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:235:827330. [Accessed: 21 December 2024]

Please login to the repository to save this object to your list.
Metadata
Title (english)Ultrasonic Plasma Engineering Toward Facile Synthesis of Single-Atom M-N4/N-Doped Carbon (M = Fe, Co) as Superior Oxygen Electrocatalyst in Rechargeable Zinc–Air Batteries
AuthorKai Chen
AuthorSeonghee Kim
AuthorMinyeong Je
AuthorHeechae Choi
AuthorZhicong Shi
AuthorNikola Vladimir
AuthorKwang Ho Kim
AuthorOi Lun Li
Author's institutionUniversity of Zagreb
Faculty of Mechanical Engineering and Naval Architecture
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Shipbuilding
Abstract (english)
As bifunctional oxygen evolution/reduction electrocatalysts, transition-metal-based single-atom-doped nitrogen-carbon (NC) matrices are promising successors of the corresponding noble-metal-based catalysts, offering the advantages of ultrahigh atom utilization efficiency and surface active energy. However, the fabrication of such matrices (e.g., well-dispersed single-atom-doped M-N-4/NCs) often requires numerous steps and tedious processes. Herein, ultrasonic plasma engineering allows direct carbonization in a precursor solution containing metal phthalocyanine and aniline. When combining with the dispersion effect of ultrasonic waves, we successfully fabricated uniform single-atom M-N-4 (M = Fe, Co) carbon catalysts with a production rate as high as 10 mg min(-1). The Co-N-4/NC presented a bifunctional potential drop of Delta E = 0.79 V, outperforming the benchmark Pt/C-Ru/C catalyst (Delta E = 0.88 V) at the same catalyst loading. Theoretical calculations revealed that Co-N-4 was the major active site with superior O-2 adsorption-desorption mechanisms. In a practical Zn-air battery test, the air electrode coated with Co-N-4/NC exhibited a specific capacity (762.8 mAh g(-1)) and power density (101.62 mW cm(-2)), exceeding those of Pt/C-Ru/C (700.8 mAh g(-1) and 89.16 mW cm(-2), respectively) at the same catalyst loading. Moreover, for Co-N-4/NC, the potential difference increased from 1.16 to 1.47 V after 100 charge-discharge cycles. The proposed innovative and scalable strategy was concluded to be well suited for the fabrication of single-atom-doped carbons as promising bifunctional oxygen evolution/reduction electrocatalysts for metal-air batteries.
Keywords (english)
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionPublished version
Journal titleNano-Micro Letters
Numberingvol. 13, no. 1, 60
p-ISSN2311-6706
e-ISSN2150-5551
DOIhttps://doi.org/10.1007/s40820-020-00581-4
URN:NBNurn:nbn:hr:235:827330
Publication2021-01-21
Document URLhttps://link.springer.com/10.1007/s40820-020-00581-4
Type of resourceText
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2024-07-02 12:26:28